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MATERIAL SAFETY DATA SHEET
SECTION 1 - MATERIAL IDENTIFICATION_____________________________________________________________ Page 1 of 2
PRODUCT NAME: RAKA EPOXY HARDENER 350                                       ADDRESS: RAKA INC. 3490 Oleander Ave. Ft. Pierce. Fl. 34982
MANUFACTURER: RAKA INC.                                                                MSDS REVISION NUMBER: 1
TELEPHONE NUMBER: (772)489-4070                                                   DATE PREPARED: 6-1-2015
EMERGENCY OVERVIEW
HMIS HEALTH RATING    2                                                  FLAMMABILITY      1                                            REACTIVITY      0
PHYSICAL FORM                    Mobile Liquid
COLOR                                    Amber
ODOR                                      Ammoniacal
HAZARDS                                Moderate eye irritant. Moderate respiratory tract irritant. Moderate skin irritant. May cause skin sensitization.
EXTINGUISHING MEDIA Ignition will give rise to a Class B fire. In case of large fire, use: Alcohol Foam, Water Spray. In case of
small fire, use: C02, Dry Chemical, Dry Sand, or Limestone.
C.A.S. CHEMICAL NAME  Mixture                                                               EMPIRACAL FORMULA     Mixture
SYNONYMS                            None                                                                INTENDED USE                       Curing Agent
CHEMICAL FAMILY        Cycloaliphatic Amine SECTION

2 – INGREDIENTS
 #        %       CAS Number and Chemical Name

  1. > 25.00     100-51-6       BENZYL ALCOHOL
  2. <5.00      1761-71-3   METHYLENEBISCYCLOHEX AN AMINE, 4,4' -                            THE REMAINING COMPONENTS ARE TRADE SERETS.

OSHA (ACGIH) EXPOSURE LIMITS


TWA

 

STEL

 

CEILING

 

ppm

mg/m3

ppm

mg/m3

ppm

mg/m3

1. OSHA N/E

N/E

N/E

N/E

N/E

N/E

ACGIH N/E

N/E

N/E

N/E

N/E

N/E

2. OSHA N/E

N/E

N/E

N/E

N/E

N/E

ACGIH N/E

N/E

N/E

N/E

N/E

N/E

N/E = Not Established.

SECTION 3 – HEALTH HAZARDS
ROUTES OF EXPOSURE                                                TARGET ORGANS                                  HEALTH HAZARDS
Eye Contact                                                                         Eye                                                          Moderate eye irritant.
Skin Contact                                                                        Skin                                                         Moderate skin irritant.
Ingestion                                                                                                                                              May cause skin sensitization.
Skin Absorption EXPOSURE STANDARDS
No standards established for the product. Maintain air contaminant concentrations in the workplace at the lowest feasible levels. SIGNS AND SYMPTOMS OF EXPOSURE (Acute effects)
Contact with the skin may cause dryness (defeating), itching, and/or rash. Inhalation of mists may cause irritation in the respiratory tract. Contact
with the skin or eyes causes moderate eye and skin irritation, redness and discomfort which is transient. Coughing and chest pain may result.
Product is absorbed through the skin and may cause nausea, headache and general discomfort. SIGNS AND SYMPTOMS OF EXPOSURE (Possible Long Term Effects)
Repeated and/or prolonged exposure may cause allergic reaction/sensitization. Repeated and/or prolonged exposures may result in: adverse eye
effects (such as conjunctivitis or corneal damage), adverse skin effects (such as defeating, rash, or irritation ). Dryness of nasal passages may be
experienced when material is inhaled over a long period of time. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
Eye disease
Skin disorders and allergies CARCINOGENS UNDER OSHA, ACGIH, NTP, IARC, OTHER
This product contains no carcinogens in concentration of 0.1 percent or greater.

SECTION 4 - FIRST AID EYE CONTACT
Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. Seek medical advice. SKIN CONTACT
Remove product and immediately flush affected area with water for at least 15 minutes. Remove contaminated clothing and shoes. Seek medical advice. Launder contaminated clothing prior to reuse. INHALATION
Move patient to fresh air. If breathing has stopped or is labored give assisted respiration (e.g. mouth-to mouth). Prevent aspiration of vomit. Turn victim's head to the side. Seek medical advice. INGESTION
If swallowed, call a physician immediately. Note to Physicians: Remove stomach contents by gastric suction or induce vomiting only as directed
by medical personnel. Never give anything by mouth to an unconscious person.

SECTION 5 – FIRE AND EXPLOSION DATA FLASH POINT (closed cup)      103.89 C (219)F UPPER EXPLOSION LIMIT   (UEL)   No data LOWER EXPLOSION LIMIT (LEL)   No data AUTOIGNITION TEMPERATURE     No data FIRE HAZARD CLASSIFICATION (OSHA/NFPA)
Class IIIB
EXTINGUISHING MEDIA
Ignition will give rise to a Class B fire. In case of large fore use: Water Spray, Alcohol Foam. In case of small fire use: Carbon Dioxide (C02),
Dry chemical, dry sand or limestone. SPECIAL FIRE FIGHTING PROCEDURES
Firefighters should wear butyl rubber boots, gloves, and body suit and a self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARDS
May generate toxic or irritating combustion products. May generate carbon monoxide gas. May generate toxic nitrogen oxide gases. May
generate ammonia gas.

SECTION 6 - ACCIDENTAL RELEASE MEASURES CANTAMINENT TECHNIQUES
(Removal of ignition sources, diking etc.) Stop the leak, if possible. Reduce vapor spreading with a water spray. Shut off or remove all ignition sources. Construct a dike to prevent spreading. CLEAN-UP PROCEDURES
If recovery is not feasible, admix with dry soil, sand or non-reactive absorbent (sodium bisulfate) and place in a container or dumpster pending
disposal. Flush area with water spray. Clean-up personnel must be equipped with self-contained breathing apparatus and butyl rubber protective
clothing. For large spills, recover spilled material with a vacuum truck. OTHER EMERGENCY ADVICE
Wear protective clothing, boots, gloves, and eye protections

SECTION 7 - HANDLING AND STORAGE
STORAGE    Keep away from: acids, alkalis, and oxidizers. Keep in cool, dry, ventilated storage and in closed containers. Store in steel containers
located outdoors, above ground, and surrounded by dikes to contain spills or leaks. Do not store in iron or other reactive metal containers. HANDLING Avoid with skin or eyes. When handling, do not drink, or smoke.

SECTION 8 - PERSONAL PROTECTION/EXPOSURE CONTROLS
EYE PROTECTION                                                                                                              HAND PROTECTION
Splash proof goggles. In emergency, use goggles with a full-face shield.                  Neoprene rubber, impermeable, or cuffed butyl gloves.
RESPIRATORY PROTECTION                                                                                            PROTECTIVE CLOHTING
Not required under normal clothing.                                                                        Long sleeved clothing.
WORK AND HYGENIC PRACTICES
Provide accessible eye wash stations and safety showers.
Wash at end of each workshift. Use appropriate skin lotion.
Discard contaminated leather articles.

SECTION 9 - TYPICAL PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM                   Mobile liquid                                   COLOR                                                Amber
ODOR                                      Ammoniacal                                      ph                      Alkaline
VAPOR PRESSURE                 (MM Hg at 21C (70F))                     0.70
VAPOR DENSITY                    (Air=l)                                            No Data
BOILING POINT                      222.00 C (431.60 F)
MELTING POINT                    No Data
SOLUBILITY IN WATER   Slight (0.1-1 %)
SPECIFIC GRAVITY                (Water =1)                                                 1.06
MOLECULAR WEIGHT      Mixture

SECTION 10 - STABILITY AND REACTIVITY CHEMICAL STABILITY    Stable INCOMPATABILITY (Materials to avoid)
Mineral acids (i.e. sulfuric, phosphoric, etc.). Alkalis (i.e. sodium or potassium hydroxide etc.). Organic acids (i.e. acetic acid, citric acid, etc.). oxidizing agents (i.e. perchlorates, nitrates, etc.) Reactive metals (i.e. sodium, calcium, zinc, etc.). Sodium or Calcium Hypochlorite. CAUTION! N-Nitrosamines, many of which are known to be potent carcinogens, may be formed when the product comes in contact with nitrous acid, nitrites or atmospheres with high nitrous oxide concentrations. Product slowly corrodes copper, aluminum, zinc and galvanized surfaces. Amine reaction with peroxides may result in violent decomposition of peroxide possibly creating an explosion. Materials reactive with hydroxyl compounds. Nitrates, nitrosating agents. A reaction accompanies by large heat release occurs when the product is mixed with acids. Heat generated may be sufficient to cause vigorous boiling creating a hazard due to splashing or splattering of hot material.
HAZARDOUS DECOMOSITION PRODUCTS (from burning, heating or reaction with other materials).
Carbon monoxide in a fire. Carbon dioxide in a fire. Ammonia when heated. Nitrogen oxides in a fire. Irritating and toxic fumes at elevated temperatures. Nitric acid in a fire. Nitosamines and Aldehydes. Organic acid vapors. Nitrogen oxide can react with water vapors to form corrosive nitric acid. HAZARDOUS POLYMERIZATION   Will not occur.

SECTION 11 - TOXICOLOGICAL PROPERTIES
ACUTE ORATL TOXICITY (LD 50, RAT) > lOOO.OOmg/kg (no deaths) (estimate) CHRONIC/SUBCHRONIC DATA Allergic sensitization in humans. ACUTE DERMAL TOXICITY (LD50, RABBIT) > 2000.00mg/kg (no deaths) (estimate) ACUTE INHALATION TOXICITY (LC50, RAT) No data IRRITATION EFFECTS DATA Moderate irritation to the skin of a rabbit.

SECTION 12 - ECOLOGICAL INFORMATION
Ecotoxicity   no data                       Environmental Fate   no data                         Additional Information waste may present long term enviro hazards.

SECTION 13-DISPOSAL CONDERATIONS
WASTE DISPOSAL Comply with all Federal, State and Local Regulations.

SECTION 14 - TRANSPORT INFORMATION
DOT NON-BULK SHIPPING NAME RESIN COMPOUND-Not DOT Regulated. DOT BULK SHIPPING NAME   RESIN COMPOUND-Not DOT Regulated. ICAO/IATA SHIPPING DATA RESIN COMPOUND-Not LATA Regulated.                                                IMO SHIPPING DATA RESIN COMPOUND-Not IMO Regulated

 

SECTION 15 LABEL ELEMENTS
Labeling according to Regulations (EC) No 1272/2008
Hazard Pictograms:



Signal Word: DANGER

Hazard Statements:

 H302 - Harmful if swallowed
H314 - Causes severe skin burns and eye damage
H361 - Suspected of damaging fertility or the unborn child
H400 - Very toxic to aquatic life
H410 - Very toxic to aquatic life with long lasting effects

Precautionary Statements:

P201 - Obtain special instructions before use
P202 - Do not handle until all safety precautions have been read and understood
P260 - Do not breathe mist, vapors
P264 - Wash Skin thoroughly after handling
P270 - Do not eat, drink or smoke when using this product
P273 - Avoid release to the environment
P280 - Wear eye protection, face protection, protective clothing, protective gloves
P301+P312 - If swallowed: Call a POISON CENTER or doctor/physician if you feel unwell
P301+P330+P331 - If swallowed: rinse mouth. Do NOT induce vomiting
P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P308+P313 - If exposed or concerned: Get medical advice/attention P310 - Immediately call a POISON CENTER or doctor/physician.
P330 – Rinse mouth
P363 – Wash contaminated clothing before reuse
P391 – Collect spillage P405 – Store locked up
P501 – Dispose of contents/container in accordance with local, regional, national, and/or international regulations.

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